Aryl Halides and Phenols - Result Question 11

####13. The major product of the following reaction is

(a)

(c)

(2019 Main, 9 Jan I)

(b)

14 The major product of the following reaction is

$\xrightarrow[\text { (i) } EtOH]{\text { (i) } Br _2}$

(2019 Main, 9 Jan I)

(a)

(c)

(b)

(d)

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Answer:

Correct Answer: 13. $(b, d)$

Solution:

  1. Key Idea The reaction involves hydrolysis or nucleophilic substitution in first step followed by oxidation and dehydration in last step. The most important fact is that, the $Br$ group attached directly to aromatic ring will not undergo substitution in step 1.

The road map of the given reaction is as follows:

14 The road map of the given reaction is :



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