Aromatic Compounds Containing Nitrogen - Result Question 5

####5. The major product obtained in the following reaction is

(2019 Main, 8 April II)

(a)

(c)

(b)

(d)

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Answer:

Correct Answer: 5. (d)

Solution:

In step (i), $1^{\circ}$ amine is converted into isocyanide, when reacts with $CHCl _3 / KOH$. This reaction is known as carbylamine reaction. This reaction is used to detect primary amine in a compound.

In step (ii), isocyanide is reduced to secondary amine and cyanide is reduced to primary amine, and carbonyl group to alcoholic group when treated with $Pd / C / H _2$.



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