Aromatic Compounds Containing Nitrogen - Result Question 31

####32. p-chloroaniline and anilinium hydrochloride can be distinguished by

(1998,2M)

(a) Sandmeyer reaction

(b) NaHCO3

(c) AgNO3

(d) Carbylamine test

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Answer:

Correct Answer: 32. (c,d)

Solution:

  1. (C6H5N+H3Cl)+AgNO3AgCl anilinium hydrochloride precipitate No such precipitate is formed with p-chloroaniline. Also, carbylamine test will not be given by anilinium hydrochloride but p-chloroaniline give this test.


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