Aromatic Aldehydes Ketones and Acids - Result Question 6

####7. In the following reactions, the product $S$ is

(2019 Main, 12 Jan I)

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Answer:

Correct Answer: 7. $(a)$

Solution:

  1. Key Idea Grignard reagent usually attacks on $>C=O$ group as :

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The question is related to above reaction only with the condition that the consumption of $R \operatorname{Mg} X$ will be more than 1 equivalent in some of the given cases.

Among the given compounds $B$, i.e.

contain additional groups which can give active hydrogens. Grignard reagents produce alkanes whenever come in contact with any group or compound which can give active hydrogen as:

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These reactions are equivalent to acid-base reactions. So, in both of these compounds more than one equivalent will be required to form Grignard products. Remember these compounds will give 2 type of products as:

(i) from the $>C=O$ group

(ii) from the group which release active hydrogen

The additional reactions involved are:



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