Haloalkanes And Haloarenes Question 5

Question 5 - 2024 (27 Jan Shift 2)

Which among the following halide/s will not show $\mathrm{S}_{\mathrm{N}} 1$ reaction:

(A) $\mathrm{H}{2} \mathrm{C}=\mathrm{CH}-\mathrm{CH}{2} \mathrm{Cl}$

(B) $\mathrm{CH}_{3}-\mathrm{CH}=\mathrm{CH}-\mathrm{Cl}$

(C)

(D)$\mathrm{CH}{3}$
$\mathrm{H}
{3} \mathrm{C}$
$\mathrm{CH}-\mathrm{Cl}$

Choose the most appropriate answer from the options given below:

(1) (A), (B) and (D) only

(2) (A) and (B) only

(3) (B) and (C) only

(4) (B) only

Show Answer

Answer (4)

Solution

Formula: SN1 reaction

Since $\mathrm{CH}{3}-\mathrm{CH}=\stackrel{+}{\mathrm{C}} \mathrm{H}$ is very unstable, $\mathrm{CH}{3}-\mathrm{CH}=\mathrm{CH}-\mathrm{Cl}$ cannot give $\mathrm{S}_{\mathrm{N}^{1}}$ reaction.