Modern Physics 1 Question 53

49. A hydrogen like atom (atomic number Z ) is in a higher excited state of quantum number n. The excited atom can make a transition to the first excited state by successively emitting two photons of energy 10.2eV and 17.0eV respectively. Alternately, the atom from the same excited state can make a transition to the second excited state by successively emitting two photons of energies 4.25eV and 5.95eV respectively.

(1994,6M)

Determine the values of n and Z.

(Ionization energy of H-atom =13.6eV )

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Answer:

Correct Answer: 49. (a) rn=n2h2ε0624πmee2 (b) n25 (c) 0.546\AA

Solution:

  1. From the given conditions

EnE2=(10.2+17)eV=27.2eV and EnE3=(4.25+5.95)eV=10.2eV

Eq. (i) - Eq. (ii) gives

E3E2=17.0eV or Z2(13.6)1419=17.0

Z2(13.6)(5/36)=17.0Z2=9 or Z=3

From Eq. (i) Z2 (13.6) 141n2=27.2

 or (3)2(13.6)141n2=27.2 or 141n2=0.222 or 1/n2=0.0278 or n2=36n=6



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