Modern Physics 1 Question 24

21. The electron in a hydrogen atom makes a transition from an excited state to the ground state. Which of the following statement is true?

(2000, 2M)

(a) Its kinetic energy increases and its potential and total energy decreases

(b) Its kinetic energy decreases, potential energy increases and its total energy remains the same

(c) Its kinetic and total energy decreases and its potential energy increases

(d) Its kinetic, potential and total energy decreases

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Solution:

  1. vn1nKE1n2 (with positive sign)

Potential energy U is negative and Un1rn

Un=14πε0Ze2rnEn1n2 (because rnn2 ) 

Similarly, total energy En1n2. (with negative sign)

Therefore, when an electron jumps from some excited state to the ground state, value of n will decrease. Therefore, kinetic energy will increase (with positive sign), potential energy and total energy will also increase but with negative sign.

Thus, finally kinetic energy will increase, while potential and total energies will decrease.

NOTE

  • For hydrogen and hydrogen-like atoms

En=13.6Z2n2eVUn=2En=27.2Z2n2eV and Kn=|En|=13.6Z2n2eV

From these three relations we can see that as n decreases, Kn will increase but En and Un will decrease.

  • As an electron comes closer to the nucleus, the electrostatic force (which provides the necessary centripetal force) increases or speed (or KE) of the electron increases.


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