Heat and Thermodynamics 6 Question 10

14. In a given process of an ideal gas, $d W=0$ and $d Q<0$. Then for the gas

$(2001$, s)

(a) the temperature will decrease

(b) the volume will increase

(c) the pressure will remain constant

(d) the temperature will increase

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Answer:

Correct Answer: 14. (d)

Solution:

  1. From first law of thermodynamics,

$$ \begin{array}{llrl} & & d Q & =d U+d W \\ & & d Q & =d U, \text { if } d W=0 \\ \text { Since, } & & d Q & <0 \\ \text { Therefore, } & & d U & <0 \\ \text { or } & U _{\text {final }} & <U _{\text {initial }} \end{array} $$

or temperature will decrease.

NOTE Internal energy $U$ of an ideal gas depends only on the temperature of the gas. Internal energy of $n$ moles of an ideal gas is given by

$$ \begin{aligned} & U=n(f / 2) R T \\ & U \propto T \end{aligned} $$

Here, $f$ is the degree of freedom of the gas.



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