Heat and Thermodynamics 5 Question 5

5. Following figure shows two processes $A$ and $B$ for a gas. If $\Delta Q _A$ and $\Delta Q _B$ are the amount of heat absorbed by the system in two cases, and $\Delta U _A$ and $\Delta U _B$ are changes in internal energies respectively, then

(2019 Main, 9 April I)

(a) $\Delta Q _A>\Delta Q _B, \Delta U _A>\Delta U _B$

(b) $\Delta Q _A<\Delta Q _B, \Delta U _A<\Delta U _B$

(c) $\Delta Q _A>\Delta Q _B, \Delta U _A=\Delta U _B$

(d) $\Delta Q _A=\Delta Q _B ; \Delta U _A=\Delta U _B$

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Solution:

  1. According to the first law of thermodynamics,

Heat supplied $(\Delta Q)=$ Work done $(W)+$ Change in internal energy of the system $(\Delta U)$

Similarly, for process $B$,

$$ \Delta Q _A=\Delta U _A+W _A $$

Now, we know that,

$$ \Delta Q _B=\Delta U _B+W _B $$

work done for a process $=$ area under it’s $p$ - $V$ curve Here,

Thus, it is clear from the above graphs,

$$ W _A>W _B $$

Also, since the initial and final state are same in both process, so

$$ \Delta U _A=\Delta U _B $$

So, from Eqs. (i) and (ii), we can conclude that

$$ \Delta Q _A>\Delta Q _B $$



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