Heat and Thermodynamics 4 Question 3

3. One mole of an ideal gas passes through a process, where pressure and volume obey the relation p=p0[112(V0V)2].

Here, p0 and V0 are constants. Calculate the change in the temperature of the gas, if its volume changes from V0 to 2V0.

(a) 12p0V0R

(b) 14p0V0R

(c) 34p0V0R

(d) 54p0V0R

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Solution:

  1. Given process equation for 1 mole of an ideal gas is

p=p0(112(V0V)2)

Also, for 1 mole of ideal gas,

pV=RTp=RTV

So, from Eqs. (i) and (ii), we have

RTV=p0(112(V0V)2)T=p0VR(112(V0V)2)

When volume of gas is V0, then by substituting V=V0 in Eq. (iii), we get

Temperature of gas is

T1=p0V0R(112(V0V0)2)=p0V02R

Similarly, at volume, V=2V0

Temperature of gas is

T2=p0(2V0)R(112(V02V0)2)=74p0V0R

So, change in temperature as volume changes from V0 to 2V0 is

ΔT=T2T1=(7412)p0V0R=54p0V0R



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