Heat and Thermodynamics 1 Question 3

3. When 100g of a liquid A at 100C is added to 50g of a liquid B at temperature 75C, the temperature of the mixture becomes 90C. The temperature of the mixture, if 100g of liquid A at 100C is added to 50g of liquid B at 50C will be

(a) 60C

(b) 80C

(c) 70C

(d) 85C

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Solution:

  1. In first case according to principle of calorimetry, heat lost by liquid A= heat gained by liquid B

or

mASAΔTA=mBSBΔTB

where, SA is specific heat capacity of A and SB is specific heat capacity of B

100×SA(10090)=50×SB(9075)1000SA=50×15SB or 4SA=3SB

Similarly, in second case,

100×SA(100T)=50×SB(T50)

where, T= Final temperature of the mixture.

4SA(100T)=2SB(T50)

Using Eq. (i),

3SB(100T)=2SB(T50)

 or 3003T=2T100 or 5T=400 or T=80C



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