Qualitative Analysis - Result Question 37
####40. The final solution contains
(a) $\left[Pb\left(NH _3\right) _4\right]^{2+}$ and $\left[CoCl _4\right]^{2-}$
(b) $\left[Al\left(NH _3\right) _4\right]^{3+}$ and $\left[Cu\left(NH _3\right) _4\right]^{2+}$
(c) $\left[Ag\left(NH _3\right) _2\right]^{+}$and $\left[Cu\left(NH _3\right) _4\right]^{2+}$
(d) $\left[Ag\left(NH _3\right) _2\right]^{+}$and $\left[Ni\left(NH _3\right) _6\right]^{2+}$
Passage 4
$p$-amino-N, N-dimethylaniline is added to a strongly acidic solution of $X$. The resulting solution is treated with a few drops of aqueous solution of $Y$ to yield blue colouration due to the formation of methylene blue. Treatment of the aqueous solution of $Y$ with the reagent potassium hexacyanoferrate (II) leads to the formation of an intense blue precipitate. The precipitate dissolves on excess addition of the reagent. Similarly, treatment of the solution of $Y$ with the solution of potassium hexacyanoferrate (III) leads to a brown colouration due to the formation of $Z$.
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Answer:
Correct Answer: 40. (d)
Solution:
- Since, in the beginning, concentrated $AgNO _3$ solution was taken, some $AgNO _3$ remain in solution which gives white precipitate of $AgCl$ on addition of $NaCl$. The precipitate finally dissolve in ammonia and $Cu^{2+}$ present in solution also forms complex with ammonia as
$$ \begin{aligned} & Cu\left(NO _3\right) _2+4 NH _3(a q) \rightarrow\left[Cu\left(NH _3\right) _4\right]^{2+}+2 NO _3^{-} \ & \text {Blue } \ & AgCl(s)+2 NH _3(a q) \rightarrow\left[Ag\left(NH _3\right) _2\right]^{+}+Cl^{-} \end{aligned} $$
The comprehension describing methylene-blue test.
Blue solution
Therefore,
