Qualitative Analysis - Result Question 37

####40. The final solution contains

(a) [Pb(NH3)4]2+ and [CoCl4]2

(b) [Al(NH3)4]3+ and [Cu(NH3)4]2+

(c) [Ag(NH3)2]+and [Cu(NH3)4]2+

(d) [Ag(NH3)2]+and [Ni(NH3)6]2+

Passage 4

p-amino-N, N-dimethylaniline is added to a strongly acidic solution of X. The resulting solution is treated with a few drops of aqueous solution of Y to yield blue colouration due to the formation of methylene blue. Treatment of the aqueous solution of Y with the reagent potassium hexacyanoferrate (II) leads to the formation of an intense blue precipitate. The precipitate dissolves on excess addition of the reagent. Similarly, treatment of the solution of Y with the solution of potassium hexacyanoferrate (III) leads to a brown colouration due to the formation of Z.

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Answer:

Correct Answer: 40. (d)

Solution:

  1. Since, in the beginning, concentrated AgNO3 solution was taken, some AgNO3 remain in solution which gives white precipitate of AgCl on addition of NaCl. The precipitate finally dissolve in ammonia and Cu2+ present in solution also forms complex with ammonia as

Cu(NO3)2+4NH3(aq)[Cu(NH3)4]2++2NO3 Blue  AgCl(s)+2NH3(aq)[Ag(NH3)2]++Cl

The comprehension describing methylene-blue test.

Blue solution

Therefore,



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