Qualitative Analysis - Result Question 11

####11. A metal nitrate reacts with $KI$ to give a black precipitate which on addition of excess of KI convert into orange colour solution. The cation of metal nitrate is

(a) $Hg^{2+}$

(b) $Bi^{3+}$

(c) $Sn^{2+}$

(d) $Pb^{2+}$

$(2005,1 M)$

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Solution:

  1. $Bi^{3+}+3 I^{-} \longrightarrow \underset{\text { Black }}{BiI _3 \downarrow} \underset{\text { excess }}{I^{-}} \underset{\substack{\text { Orange } \ \text { solution }}}{\left[BiI _4 \Gamma\right.}$


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