Organic Chemistry Basics - Result Question 75

####27. The correct combination of names for isomeric alcohols with molecular formula C4H10O is/are

(2014 Adv.)

(a) tert-butanol and 2-methylpropan-2-ol

(b) tert-butanol and 1,1-dimethylethan-1-ol

(c) n-butanol and butan-1-ol

(d) iso-butyl alcohol and 2-methylpropan-1-ol

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Answer:

Correct Answer: 27. (a,d)

Solution:

  1. PLAN This problem is based on structure and nomenclature of organic compound.

Draw structure of each compound and write IUPAC name of the given compound.

Match the molecular formula of given compound with molecular formula of compound given in choices.

The combination of names for possible isomeric alcohols with molecular formula C4H10O is/are

Formula Names
CH3CH2CH2CH2OH n-butyl alcohol / n-butanol
/ butan-1-ol
CH3CHCH2OH Iso-butyl alcohol / 2-methyl
propan-1-ol
CH3CH2CHOH Secondary butyl alcohol /
butan-2-ol
CH3COH Tertiary butyl alcohol /
tert butanol / 2-methyl
propan-2-ol
CH3

Hence, choices (a), (c) and (d) are correct.



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