Hydrocarbons - Result Question 91
####79. Give reasons for the following in one or two sentences :
(i) Methane does not react with chlorine in the dark.
(ii) Propene reacts with $HBr$ to give isopropyl bromide but does not give $n$-propyl bromide.
$(1983,1 M \times \mathbf{2}=\mathbf{2 M})$
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Solution:
- (i) Free radical chlorination of alkane require energy which is supplied either in the form of heat or radiation.
(ii) Addition of $HBr$ proceeds through carbocation intermediates.
