Coordination Compounds 2 Question 36

####38. Both [Ni(CO)4] and [Ni(CN)4]2 are diamagnetic. The hybridisations of nickel in these complexes respectively, are

(a) sp3,sp3

(b) sp3,dsp2

(c) dsp2,sp3

(d) dsp2,dsp2

(2008,3M)

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Answer:

Correct Answer: 38. (b)

Solution:

  1. In Ni(CO)4,Ni is sp3-hybridised while in [Ni(CN)4]2,Ni2+ is dsp2-hybridised.


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