Chemical and Ionic Equilibrium - Result Question 132

####74. The concentration of hydrogen ions in a 0.20M solution of formic acid is 6.4×103mol/L. To this solution, sodium formate is added so as to adjust the concentration of sodium formate to one mole per litre.

What will be the pH of this solution? The dissociation constant of formic acid is 2.4×104 and the degree of dissociation of sodium formate is 0.75 .

(1985,3M)

Show Answer

Solution:

  1. HCOOHH++HCOO

HCOONa10.75Na++HCOO

In the above buffer solution, the significant source of formate ion (HCOO)is HCOONa. Hence,

$$ \begin{aligned} K _a & =2.4 \times 10^{-4} \ & =\frac{\leftH^{+}\right}{[HCOOH]} \ {\left[H^{+}\right] } & =\frac{2.4 \times 10^{-4} \times 0.20}{0.75}=6.4 \times 10^{-5} \ pH & =-\log \left(6.4 \times 10^{-5}\right)=4.20 \end{aligned} $$



जेईई के लिए मॉक टेस्ट

एनसीईआरटी अध्याय वीडियो समाधान

दोहरा फलक