Chemical and Ionic Equilibrium - Result Question 106

####50. N2O4 is 25 dissociated at 37C and one atmosphere pressure. Calculate (i) Kp and (ii) the percentage dissociation at 0.1atm and 37C.

(1988,4M)

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Solution:

N2O42NO2 Total  pi:1α2α 1α1+αp2α1+αp Kp=4α21α2p=4(0.25)21(0.25)2=0.26atm

When p=0.10atm

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