Aromatic Compounds Containing Nitrogen - Result Question 20

####20. Amongst the compounds given, the one that would form a brilliant coloured dye on treatment with $NaNO _2$ in dil. $HCl$ followed by addition to an alkaline solution of $\beta$-naphthol is

(a)

(c)

(b)

(d)

(2011)

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Answer:

Correct Answer: 20. (d)

Solution:

  1. As we know, benzenediazonium salt forms brilliant coloured dye with $\beta$-naphthol, the compound under consideration must be $p$-toluidine (c) as it is a primary aromatic amine. Primary aromatic amine, on treatment with $NaNO _2$ in dil. $HCl$ forms the corresponding diazonium chloride salt.


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