Aliphatic Compounds Containing Nitrogen - Result Question 30
####32. Match each of the compounds in Column I with its characteristic reaction(s) in Column II.
(2016, Adv.)
| Column I | Column II | ||
|---|---|---|---|
| (A) |
(p) | Reduction with |
|
| (B) |
(q) | Reduction with |
|
| (C) |
(r) | Development of foul smell on treatment with chloroform and alcoholic KOH. |
|
| (D) |
(s) | Reduction with diisobutylaluminium hydride (DIBAL-H) |
|
| (t)Alkaline hydrolysis |
Subjective Questions
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Answer:
Correct Answer: 32.
Solution:
| Column I | Column II | |
|---|---|---|
| (A) | Gives amine with Gives aldehyde with diisobutyl- aluminium hydride. Gives carboxylic acid on alkaline hydrolysis. |
|
| (B) | Reduced to alcohol with diisobutylaluminium hydride into aldehyde. Undergo alkaline hydrolysis. |
|
| (C) | Reduced to butanol when treated with |
