Aliphatic Compounds Containing Nitrogen - Result Question 21

####22. Benzamide on treatment with $POCl _3$ gives

(a) aniline

(b) benzonitrile

(c) chlorobenzene

(d) benzyl amine

(2004)

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Answer:

Correct Answer: 22. (b)

Solution:

  1. $C _6 H _5-\stackrel{O}{C}-NH _2 \xrightarrow{POCl _3} C _6 H _5-C \equiv N+H _2 O$

$POCl _3$ brings about dehydration of primary amide.



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