Aliphatic Compounds Containing Nitrogen - Result Question 11

####12. The major product obtained in the following reaction is

(2019 Main, 9 Jan II) (a)

(c)

(b)

(d)

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Answer:

Correct Answer: 12. (b)

Solution:

  1. Rate of acetylation : NH2>OH because N-bases are stronger than O-bases. Size of N-atom is larger than O-atom and at the same time, N atom is less electronegative than O-atom. So, N-atom of the N¨H2 group can donate its lone pair of electrons (Lewis basicity) more easily than that of O atom of the O¨ H group.



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