Aldehydes and Ketones - Result Question 34

####35. After completion of the reactions (I and II), the organic compound (s) in the reaction mixtures is/are

(2013)

Reaction I

Reaction II

(a) reaction I :P and reaction II :P

(b) reaction I:U, acetone and reaction II :Q, acetone

(c) reaction I:T,U, acetone and reaction II :P

(d) reaction I:R, acetone and reaction II :S, acetone

Show Answer

Answer:

Correct Answer: 35. (a)

Solution:

  1. Plan When acetone reacts with Br2 in basic medium, bromoform is formed.

Reaction I CH3COCH3+3Br2+4NaOH

1mol3mol 13mol1mol CH3COONa+CHBr3+3NaBr+3H2O (T) (U)

When CH3COCH3 and Br2 are in equimolar quantity, all the Br2 (limiting reactant) is converted into desired products and 2/3 mole of CH3COCH3 remains unreacted, being in excess. When acetone reacts with Br2 in acidic medium, there is monobromination of acetone.

Reactions II

CH3COCH3+Br2CH3COOHCH3COCH2Br+HBr 1mol1mol (P)

CH3COCH3 and Br2 react in 1:1 mole ratio and (P) is formed. In reaction I,(U) and (T) are formed and acetone (reactant) remains unreacted. In reaction II, (P) is formed.



जेईई के लिए मॉक टेस्ट

एनसीईआरटी अध्याय वीडियो समाधान

दोहरा फलक