Some Basic Concepts Of Chemistry Question 63

Question: 3.92 g of ferrous ammonium sulphate crystals are dissolved in 100 mL of water. 20 mL of this solution requires 18 mL of potassium permaganate during titration for complete oxidation. The weight of KMnO4 present in one litre of the solution of

Options:

A) 3.47 g

B) 12.38 g

C) 1.23 g

D) 34.76 g

Show Answer

Answer:

Correct Answer: A

Solution:

[a] Normality of ferrous amm sulphate =3.92×1000392×100=0.1 (Eq. wt of FAS is 392)

M1V1=M2V2 20×0.1=18×N2

N2=0.111 1 g ev. of KMnO4=31.6g 0.111 g ev. of KMnO4=31.6×0.111=3.5g.



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