Solutions Question 56

Question: A 0.001 molal solution of $ [Pt{{(NH_3)}4}Cl_4] inwaterhadafreezingpointdepressionof {{0.0054}^{o}}C .If K{f} $ for water is 1.80, the correct formulation for the above molecule is [Kerala CET (Med.) 2003]

Options:

A) [Pt(NH3)4Cl3],Cl

B) [Pt(NH3)4Cl],Cl2

C) [Pt(NH3)4Cl2],Cl3

D) [Pt(NH3)4Cl4]

Show Answer

Answer:

Correct Answer: B

Solution:

ΔTf=imkf ; 0.0054=i×1.8×0.001

i=3 so it is [Pt(NH3)4Cl]Cl2 .



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