Solutions Question 360

Question: 0.010M solution an acid HA freezes at 0.0205C . If  Kf for water is 1.860Kkgmol1 , the ionization constant of the conjugate base of the acid will be (assume 0.010M=0.010m )

Options:

A) 1.1×104

B) 1.1×103

C) 9.0×1011

D) 9.0×1012

Show Answer

Answer:

Correct Answer: C

Solution:

ΔTf(normal)=Kfm=1.86×0.01=0.0186;

i=ΔTf(obs)ΔTf(nor)=0.02050.0186=1.10=1+α;

α=0.1

Ka=Ca21α=0.01×0.1210.1=19×103;

Ka=KwKa=10×1014×9×103=9×1011



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