Solutions Question 359

Question: Which of the following has been arranged in the increasing order of freezing poin'

Options:

A) 0.025MKNO3<0.1MNH2CSNH2 <0.05M,BaCl2<0.1MNaCl

B) 0.1M,NaCl<0.05M,BaCl2 <0.1M,NH2CSNH2<0.025M,KNO3

C) 0.1M,NH2CSNH2<0.1M,NaCl <0.05M,BaCl2<0.025M,KNO3

D) 0.025M,KNO3<0.05M,BaCl2 <0.1M,NaCl<0.1M,NH2CSNH2

Show Answer

Answer:

Correct Answer: B

Solution:

Greater is the effective molarity (i×C), higher the ΔTf value and lower the freezing point.

(i) 0.1M,NaCl=i×C=2×0.1=0.2

(ii) 0.05M,BaCl2=i×C=3×0.05=0.15

(iii) 0.1M,NH2CSNH2=i×C=1×0.1=0.1

(iv) 0.025M,KNO3=i×C=2×0.025=0.50

Thus, order is (i) < (ii) < (iii) < (iv)



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