Solutions Question 116

Question: A solution has a 1 : 4 mole ratio of pentane to hexane. The vapour pressure of the pure hydrocarbons at 20°C are 440 mmHg for pentane and 120 mmHg for hexane. The mole fraction of pentane in the vapour phase would be [CBSE PMT 2005]

Options:

A) 0.549

B) 0.200

C) 0.786

D) 0.478

Show Answer

Answer:

Correct Answer: D

Solution:

PT=Pp0xp+Ph0xh = 440×15+120×45 = 88+96 = 184 ; Pp0xp=ypPT ; 88184=yp

yp=0.478



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