Redox Reactions And Electrochemistry Ques 737

Question: Zn-Hg is prepared by electrolysis of aqueous ZnCl2 using Hg cathode (9g). How much current is to be passed through ZnCl2 solution for 1000 s to prepare a Zn-Hg with 25% Zn by weight (Zn = 65.4):

Options:

A) 5.6 A

B) 7.2 A

C) 8.85 A

D) 11.2 A

Show Answer

Answer:

Correct Answer: C

Solution:

[c] Let x gram of Zn deposited on 9 g of Hg % of Zn in amalgam =x9+x×100=25

x=3g Eq. of Zn=3×265.4 Current,=665.4×96500100=8.85A



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