Redox Reactions And Electrochemistry Ques 640

Question: Equivalent conductance at infinite dilution, λ of NH4Cl,,NaOH and NaCl are 128.0,217.8 and 109.3ohm1cm2eq1 respectively. The equivalent conductance of 0.01NNH2OH is 9.30ohm1,cm2eq1 then the degree of ionization of NH4OH at this temperature would be

Options:

A) 0.04

B) 0.1

C) 0.39

D) 0.62

Show Answer

Answer:

Correct Answer: A

Solution:

[a] Λeq(NH4OH)=Λeq(NH4Cl)+Λeq(NaOH)Λeq(NaCl)

=129.8+217.8109.3=238.3ohm1cm2eq1

α=ΛeqΛeq=9.30238.3=0.04



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