Redox Reactions And Electrochemistry Ques 38

Question: The molar conductances of $ NaCl,,HCl $ and $ CH_3COONa $ at infinite dilution are 126.45, 426.16 and $ 91,oh{m^{-1}},cm^{2},mo{l^{-1}} $ respectively. The molar conductance of $ CH_3COOH $ at infinite dilution is [CBSE PMT 1997]

Options:

A) $ 201.28,oh{m^{-1}},cm^{2},mo{l^{-1}} $

B) $ 390.71,oh{m^{-1}}cm^{2},mo{l^{-1}} $

C) $ 698.28,oh{m^{-1}},cm^{2},mo{l^{-1}} $

D) $ 540.48,oh{m^{-1}}cm^{2},mo{l^{-1}} $

Show Answer

Answer:

Correct Answer: B

Solution:

$ \wedge _m^{o}(CH_3COOH)= $ $ {{\wedge }^{o}}(CH_3COONa) $ $ +{{\wedge }^{o}}(HCl)-{{\wedge }^{o}}(NaCl) $ $ =91+426.16-126.45=390.71oh{m^{-1}}cm^{2}mo{l^{-1}} $ .



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