Redox Reactions And Electrochemistry Ques 223

Question: Cr2O72+II2+Cr3+ Ecell0=0.79 V ECr2O720=1.33 V, EI20 is [BVP 2004]

Options:

A) 0.10 V

B) +0.18 V

C) 0.54 V

D) 0.54 V

Show Answer

Answer:

Correct Answer: D

Solution:

I get oxidised to I2 hence will form anode and Cr2O72 get reduced to Cr3+ hence will form cathode.

Ecell0=ECathode0EAnode0 ;

ECell0=ECr2O72EI20

0.79=1.33EI20 ; EI20=1.330.79 ; EI20=0.54 V .



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