P-Block Elements Ques 62

Question: Carbon suboxide $ C_3O_2 $ has

[DCE 2003]

Options:

A) Linear structure

B) Bent structure

C) Trigonal planar structure

D) Distorted tetrahedral structure

Show Answer

Answer:

Correct Answer: A

Solution:

Carbon suboxide has linear structure with $ C-C $ bond length equal to $ 130\ {\AA} $ and $ C-O $ bond length equal to $ 120\ {\AA} $ . $ O=C=C=C=O\rightarrow {{O}^{-}}-C\equiv C-C\equiv {{O}^{+}} $



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