Equilibrium Question 890

Question: Select the best indicator from the given table for titration of 20 mL of 0.02,MCH3COOH with 0.02 M NaOH. Given pKa,(CH3COOH)=4.74

Indicator pH Range (I) Bromothy mol blue 6.0-7.6 (II) Thymolphthalein 9.3-11.05 (III) Malachite green 11.4-13 (IV) M-Cresol purple 7.4-9.0

Options:

A) I

B) II

C) III

D) IV

Show Answer

Answer:

Correct Answer: D

Solution:

At equivalent point pH=12[pKw+pKa+log,C]

=12[14+4.742]=8.37

where [Salt]=milli - moles of acidTotal volume=

20×0.0220+20=0.01

For best indicator pH at equivalent point should be between colour transition range of indicator.



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