Equilibrium Question 890

Question: Select the best indicator from the given table for titration of 20 mL of $ 0.02,MCH_3COOH $ with 0.02 M NaOH. Given $ pK_{a},(CH_3COOH)=4.74 $

Indicator pH Range (I) Bromothy mol blue 6.0-7.6 (II) Thymolphthalein 9.3-11.05 (III) Malachite green 11.4-13 (IV) M-Cresol purple 7.4-9.0

Options:

A) I

B) II

C) III

D) IV

Show Answer

Answer:

Correct Answer: D

Solution:

At equivalent point $ pH=\frac{1}{2}[pK_{w}+pK_{a}+\log ,C] $

$ =\frac{1}{2}[14+4.74-2]=8.37 $

where $ [Salt]=\frac{\text{milli - moles of acid}}{\text{Total volume}}= $

$ \frac{20\times 0.02}{20+20}=0.01 $

For best indicator pH at equivalent point should be between colour transition range of indicator.



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