Equilibrium Question 853

Question: The dissociation constants of a weak acid HA and weak base BOH are $ 2\times {10^{-5}} $ and $ 5\times {10^{-6}} $ respectively. The equilibrium constant for the neutralisation reaction of the two is

Options:

A) $ 1.0\times 10^{4} $

B) $ 1.0\times {10^{-4}} $

C) $ 1.0\times {10^{-10}} $

D) $ 2.5\times {10^{-1}} $

Show Answer

Answer:

Correct Answer: A

Solution:

$ HA+BOH\rightarrow BA+H_2O $

$ \therefore K_{H}=\frac{K_{w}}{K_{a}\times K_{b}}. $ The inverse of $ K_{H} $ is $ K_{c}=\frac{K_{a}\times K_{b}}{K_{w}}. $

$ =\frac{2\times {10^{-5}}\times 5\times {10^{-6}}}{1\times {10^{-14}}}=1.0\times 10^{4} $



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