Equilibrium Question 655

Question: Calculate the partial pressure of carbon monoxide from the following $ CaC{O_{3(s)}}\xrightarrow{\Delta }Ca{O_{(s)}}+CO_2\uparrow $ ; $ K_{p}=8\times {10^{-2}} $

$ C{O_{2(g)}}+{C_{(s)}}\to 2C{O_{(g)}} $ ; $ K_{p}=2 $

$ $ [Orissa JEE 2004]

Options:

A) 0.2

B) 0.4

C) 1.6

D) 4

Show Answer

Answer:

Correct Answer: B

Solution:

Given, $ CaCO_3(s)\xrightarrow{\Delta },CaO(s)+CO_2(g)\uparrow $

$ C(s)+CO_2(g) $ ⇌ $ 2CO(g) $

$ Kp_2=\frac{{{[pCO]}^{2}}}{[pCO_2]} $ ; $ pCO=\sqrt{[Kp_1\times Kp_2]} $

$ pCO=\sqrt{[8\times {10^{-2}}\times 2]}=\sqrt{16\times {10^{-2}}} $

$ =4\times {10^{-1}}=0.4 $



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