Equilibrium Question 286

Question: If the solubility product of AgBrO3 and Ag2SO4 are 5.5×105 and 2×105 respectively, the relationship between the solubilities of these can be correctly represented as [EAMCET 1985]

Options:

A) SAgBrO3>SAg2SO4

B) SAgBrO3<SAg2SO4

C) SAgBrO3=SAg2SO4

D) SAgBrO3SAg2SO4

Show Answer

Answer:

Correct Answer: B

Solution:

Ag2SO42Ag+4S2,+SO4,S,

Ksp=4S3;Ksp=2×105

S=2×10543=0.017,m/l

=1.7×102 Ag BrO3Ag+S,+BrO3S,

Ksp=S2;Ksp=5.5×105

S=5.5×105=7.4×103,m/l.



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