D-And F-Block Elements Ques 482

Question: A red solid is insoluble in water. However it becomes soluble if some KI is added to water. Heating the red solid in a test tube results in liberation of some violet coloured fumes and droplets of a metal appear on the cooler parts of the test tube. The red solid is

Options:

A) HgI2

B) HgO

C) Pb3O4

D) (NH4)2Cr2O7

Show Answer

Answer:

Correct Answer: A

Solution:

When KI is added to mercuric iodide it disssolve in it and form complex. HgI2red,,solid(insoluble),+KIK2[HgI4](soluble), On heating HgI2 decomposes as HgI2Hg+I2(violetvapours),



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