Chemical Thermodynamics Question 420

Question: The lattice energy of solid NaCl is 180kcalmol1 and enthalpy of solution is 1kcalmol1 If the hydration energies of Na+ and Cl ions are in the ratio 3 : 2, what is the enthalpy of hydration of sodium ion-

Options:

A) 107.4kcalmol1

B) 107.4kcalmol1

C) 71.6kcalmol1

D) 71.6kcalmol1

Show Answer

Answer:

Correct Answer: A

Solution:

  • ΔHhyd.=ΔHsol.ΔHlattice

=1180=179kcal,mol1 Then ΔHhyd.=(Na+)+ΔHhyd.(Cl)=179 or ΔHhyd.=(Na+)+23ΔHhyd.=179 or ΔHhyd.=(Na+)=107.4,kcal,mol1



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