Chemical Kinetics Question 79

Question: In a first order reaction the concentration of reactant decreases from 800,mol/dm3 to 50,mol/dm3 is 2×102sec . The rate constant of reaction in sec1 is [IIT-JEE (Screening) 2003]

Options:

A) 2×104

B) 3.45×105

C) 1.386×102

D) 2×104

Show Answer

Answer:

Correct Answer: C

Solution:

k=2.303tlog10aax ; t=2×102,a=800,ax=50

k=2.3032×102log1080050=2.3032×102log1016

=2.3032×102log1024=2.3032×104×4×0.301

=1.38×102s1



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