Atomic Structure Question 490

Question: For a hypothetical hydrogen like atom, the potential energy of the system is given by $ U(r)=\frac{-ke^{2}}{r^{4}} $ where r is the distance between the two particles. If Bohr’s model of quantization of angular momentum is applicable, then velocity of particle is given by

Options:

A) $ \frac{nh}{16,ke{{\pi }^{2}},{m^{3/2}}} $

B) $ \frac{n^{2}h^{2}}{18,k^{2}e^{2}{{\pi }^{2}},m^{3}} $

C) $ \frac{n^{3}h^{3}}{18,k^{2}e^{2}{{\pi }^{3}},m^{4}} $

D) $ \frac{n^{2}h^{2}}{4\sqrt{2},ke{{\pi }^{2}}{m^{3/2}}} $

Show Answer

Answer:

Correct Answer: D

Solution:

  • $ \frac{d[U(r)]}{dr}=\frac{4ke^{2}}{r^{5}}=force $ $ \frac{4ke^{2}}{r^{5}}=\frac{mv^{2}}{r} $ and $ mvr=\frac{nh}{2\pi } $ or $ r=\frac{nh}{2\pi mv}\Rightarrow \frac{1}{r}=\frac{2\pi mv}{nh} $ $ 4ke^{2}\times \frac{1}{r^{5}}=\frac{mv^{2}}{r} $ $ 2ke^{2}\times \frac{1}{r^{4}}=mv^{2} $ $ 2ke^{2}\times \frac{16{{\pi }^{4}}m^{4}v^{4}}{n^{4}h^{4}}=mv^{2} $ $ v^{2}=n^{4}h^{4}/32ke^{2}{{\pi }^{4}}m^{3} $ $ v=\frac{n^{2}h^{2}}{4\sqrt{2}ke{{\pi }^{2}}{m^{3/2}}} $


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