Kinetic Theory Of Gases And Equation Of Ideal Gas Topic

Formulae and Equations related to Kinetic Theory of Gases and Ideal Gas Laws: 1. Mean free path of a gas molecule:

λ=kBT2πd2P

Where:

  • (\lambda) is the mean free path in meters (m)
  • (k_B) is the Boltzmann constant ( 1.380649 \times 10^{-23} \ J/K)
  • (T) is the temperature in Kelvin (K)
  • (d) is the molecular diameter in meters (m)
  • (P) is the pressure in Pascals (Pa)

2. Graham’s law of effusion:

r1r2=M2M1

Where:

  • (r_1) and (r_2) are the effusion rates of two different gases.
  • (M_1) and (M_2) are the molar masses of the two gases.

3. Adiabatic expansion of an ideal gas:

PVγ=Constant

Where:

  • (P) is the pressure.
  • (V) is the volume.
  • (\gamma) is the ratio of specific heats (C_P/C_V)

4. Van der Waals equation of state for real gases:

(P+an2V2)(Vnb)=nRT

Where:

  • (a) and (b) are constants that depend on the gas
  • (n) is the number of moles of gas.
  • (R) is the ideal gas constant.

5. Compressibility factor:

Z=PVnRT

Where (Z) is compressibility factor.

6. Heat capacity at constant volume of an ideal gas:

CV=32nR

Where:

  • (C_{V}) is the heat capacity at constant volume in joules per Kelvin per mole ( J/(mol-K)).
  • (n) is the number of moles of gas
  • (R) is the ideal gas constant.

7. Heat capacity at constant pressure of an ideal gas:

CP=52nR

Where:

  • (C_P) is the heat capacity at constant pressure in joules per Kelvin per mole ( J/(mol-K)).
  • (n) is the number of moles of gas
  • (R) is the ideal gas constant.


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