The F And D Block Elements

The f- and d- block elements

The f-block elements:

  • Lanthanides:

  • Elements 57 (Lanthanum) to 71 (Lutetium)

  • Also called the rare earth metals

  • All are metals

  • Have a silvery-white appearance

  • Are soft and malleable

  • React easily with oxygen, water, and acids

  • Form trivalent ions (3+)

  • The atomic masses is very close to each other.

  • In Lanthanide series, the number of 4f- electrons increases from one to fourteen.

  • Actinides:

  • Elements 89 (Actinium) to 103 (Lawrencium)

  • Also called the actinide elements

  • All are metals

  • Are radioactive Have melting points higher than lanthanides.

  • Have very short half lives

  • Form trivalent ions (3+)

  • In Actinide series, the number of 5f- electrons increases from one to fourteen.

Similarities between f-block elements:

  • All are metals

  • Have large atomic and ionic radii

  • Have low ionization energies

  • Form basic oxides and hydroxides

  • Form colored compounds

  • Both the series show a gradual change in the properties known as Lanthanide contraction and Actinide contraction.

  • Both exhibit variable oxidation states.

  • Differences between f-block elements:

  • Lanthanide ions are colorless, while actinide ions are colored.

  • Actinides are radioactive whereas Lanthanides are not.

The d-block elements:

  • Elements in the 18 Groups of the periodic table
  • Called transition elements because of the transitional nature of their properties.
  • Contains three rows that are labeled as 3d, 4d and 5d.
  • Elements belonging to the 3d series are called First transition series whereas those belonging to 4d and 5d are called Second and third transition series respectively.
  • There are ten 3d-transition elements, ranging from scandium (Sc) to zinc (Zn).
  • The d-block elements exhibit a wide variety of colors due to the partial filling of the d-orbitals.

Similarities between d-block elements:

  • All are metals (except Hg)
  • All are hard and lustrous
  • All are fairly high in density
  • Form colored compounds
  • Form complexes
  • Undergo catalytic reactions

Differences between d-block elements:

  • They show variation in oxidation states
  • Their melting and boiling points increase on moving down a group

General properties of d- and f- block elements:

  • Both d and f block elements have large atomic radii
  • Both exhibit variable oxidation state:
  • Variable magnetic properties
  • Catalytic properties
  • Complex formation
  • Transition metals are used as alloys, while actinides are used for controlled chain reactions.


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