The F And D Block Elements
The f- and d- block elements
The f-block elements:
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Lanthanides:
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Elements 57 (Lanthanum) to 71 (Lutetium)
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Also called the rare earth metals
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All are metals
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Have a silvery-white appearance
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Are soft and malleable
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React easily with oxygen, water, and acids
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Form trivalent ions (3+)
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The atomic masses is very close to each other.
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In Lanthanide series, the number of 4f- electrons increases from one to fourteen.
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Actinides:
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Elements 89 (Actinium) to 103 (Lawrencium)
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Also called the actinide elements
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All are metals
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Are radioactive Have melting points higher than lanthanides.
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Have very short half lives
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Form trivalent ions (3+)
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In Actinide series, the number of 5f- electrons increases from one to fourteen.
Similarities between f-block elements:
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All are metals
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Have large atomic and ionic radii
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Have low ionization energies
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Form basic oxides and hydroxides
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Form colored compounds
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Both the series show a gradual change in the properties known as Lanthanide contraction and Actinide contraction.
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Both exhibit variable oxidation states.
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Differences between f-block elements:
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Lanthanide ions are colorless, while actinide ions are colored.
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Actinides are radioactive whereas Lanthanides are not.
The d-block elements:
- Elements in the 18 Groups of the periodic table
- Called transition elements because of the transitional nature of their properties.
- Contains three rows that are labeled as 3d, 4d and 5d.
- Elements belonging to the 3d series are called First transition series whereas those belonging to 4d and 5d are called Second and third transition series respectively.
- There are ten 3d-transition elements, ranging from scandium (Sc) to zinc (Zn).
- The d-block elements exhibit a wide variety of colors due to the partial filling of the d-orbitals.
Similarities between d-block elements:
- All are metals (except Hg)
- All are hard and lustrous
- All are fairly high in density
- Form colored compounds
- Form complexes
- Undergo catalytic reactions
Differences between d-block elements:
- They show variation in oxidation states
- Their melting and boiling points increase on moving down a group
General properties of d- and f- block elements:
- Both d and f block elements have large atomic radii
- Both exhibit variable oxidation state:
- Variable magnetic properties
- Catalytic properties
- Complex formation
- Transition metals are used as alloys, while actinides are used for controlled chain reactions.