Chemical Kinetics
For JEE exam:
- Rate of a reaction: It is the change in concentration of reactants or products with respect to time.
- Factors affecting the rate of a reaction:
- Concentration: The rate of a reaction increases with increase in concentration of reactants.
- Temperature: The rate of a reaction increases with increase in temperature.
- Surface area: The rate of a reaction increases with increase in surface area of the reactants.
- Catalysts: The presence of a catalyst increases the rate of a reaction without being consumed in the reaction.
- Rate constant: The rate constant is a proportionality constant that relates the rate of a reaction to the concentrations of the reactants.
- Order of reaction: The order of a reaction is the sum of the exponents of the concentrations of the reactants in the rate law.
- Molecularity of a reaction: The molecularity of a reaction is the number of molecules that participate in the rate-determining step of the reaction.
- Integrated rate equations: The integrated rate equations are mathematical equations that relate the concentration of reactants or products to time.
- Arrhenius equation: The Arrhenius equation relates the rate constant of a reaction to the activation energy and temperature.
- Collision theory of reaction rates: The collision theory of reaction rates states that the rate of a reaction is proportional to the number of collisions between the reacting molecules.
- Transition state theory: The transition state theory states that the rate of a reaction is determined by the formation of a high-energy transition state.
- Lindemann mechanism: The Lindemann mechanism is a theory of unimolecular reactions that involves the formation of an excited molecule that then reacts with another molecule.
- Hinshelwood mechanism: The Hinshelwood mechanism is a theory of heterogeneous reactions that involves the adsorption of reactants onto a surface and subsequent reaction.
- Chain reactions and free radical mechanisms: Chain reactions are reactions that involve a series of steps, each of which produces a free radical that reacts with another molecule to continue the chain. Free radical mechanisms are chain reactions that involve the formation and reaction of free radicals.
For CBSE board exam:
- Concept of rate of reaction: It refers to how quickly a chemical reaction takes occurs.
- Factors affecting the rate of a reaction:
- Concentration: Higher concentrations lead to faster reactions.
- Temperature: Increased temperatures accelerate reactions.
- Surface Area: Larger surface areas for solids and greater contact for liquids and gases enhances reactions.
- Catalysts: These are substances that speed up reactions without getting consumed in the process.
- Graphical representation of the rate of the reaction: You can plot a graph with time (x-axis) and concentration or pressure (y-axis) to get a visual representation of the reaction’s progress.
- Order of a reaction: Defines how the reaction rate is related to the concentration of reactants involved, calculated by the rate law.
- Units of rate constant: This depends on the order of reaction, for first order it’s s^(-1), for second order it’s dm^3 mol^(-1) s^(-1).
- Half-life of a reaction: The time taken for the concentration of reactants to reduce by half of the original value.
- Arrhenius equation and energy barrier: The equation connects rate constant (k), activation energy (Ea), universal gas constant (R), and temperature (T). It showcases how increasing the temperature raises the reaction rate.
- Effect of temperature on rate constant: Higher temperatures increase rate constant.
- Collision theory of reaction rate (qualitative treatment): This theory suggests that particles have to collide to bring about a reaction, and effective collisions give rise to products.