Thermodynamics Question 329

Question: P.T graph of an ideal gas of equal number of moles of different volumes are plotted as shown. Choose the correct answer

Options:

A) $ V _{1}=V _{2}>V _{3}=V _{4} $

B) $ V _{1}=V _{2}<V _{3}=V _{4} $

C) $ V _{1}=V _{2}=V _{3}=V _{4} $

D) $ V _{4}>V _{3}>V _{2}>V _{1} $

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Answer:

Correct Answer: A

Solution:

[a] In isochoric process,

$ V= $ constant or $ P\alpha T $ i.e., P-T graph is a straight line passing through origin.

But since $ P=(nRT)\frac{1}{V} $

Slope of the straight line $ \alpha \frac{1}{V} $

$ {{(\text{slope)}} _{12}}<{{(\text{slope)}} _{34}} $

$ V _{1}=V _{2}>V _{3}=V _{4} $



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