Thermodynamics Question 327

Question: A 100 kg piston encloses 32 g of oxygen gas at a temperature of 27oC in a vertical cylinder of base area of 4dm2 . The air pressure outside is 1×105Pa . The axis of the cylinder is vertical, and the piston can move in it without friction. How much heat is to be transferred to the gas to raise the piston by 20 cm. Use R=253J/mol/K

Options:

A) 3500 J

B) 350 J

C) 7000 J

D) 750 J

Show Answer

Answer:

Correct Answer: A

Solution:

[a] As heat is supplied to gas, it expands against atmospheric pressure and weight of piston. Thus the pressure of gas is constant given by,

P=P0+mgA

P=1×105+100×104×102=(1+14)105

=1.25×105N/m2

It is given that,

A=4dm2=4×102m2

m=100kg

n=1mole

V=nRTP=2×102m3

Initial height of piston from base of vessel,

h=VA=2×1024×102=12m

As process is isobaric, so

T1T2=V1V2=VV+AΔh=hh+Δh

T2T1T1=Δhh

ΔQ=nCp(T2T1)=n.Cp.T1hΔh

=72×253×3000.5×0.2=3500 J



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