Thermodynamics Question 271

Question: The variation of internal energy (U) with the pressure (P) of 2.0 mole gas in cyclic process abcda. The temperature of gas at c and d are 300 K and 500 K. calculate the heat absorbed by the gas during the process.

Options:

A) 400 R In 2

B) 200 R In 2

C) 100 R In 2

D) 300 R In 2

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Answer:

Correct Answer: A

Solution:

[a] Change in internal energy for cyclic process $ ( \Delta U )=0. $

For process $ a\to b $ , (P-constant) $ {W _{a\to b}}=P\Delta V $

$ =nR\Delta T=-400R $

For process $ b\to c $ (T-constant) $ {W _{b\to c}}=-2R(300)\text{ln 2} $

For process $ c\to d $ , (P-constant) $ {W _{c\to d}}=+400R $

For process $ d\to a $ , (T-constant) $ {W _{d\to a}}=+2R(500)\text{ ln 2 } $

Net work (AW) $ ={W _{a\to b}}+{W _{b\to c}}+{W _{c\to d}}+{W _{d\to a}} $

$ \Delta W=400R\text{ ln 2} $

$ \therefore dQ=dU+dW $ , first law of thermodynamics $ \therefore dQ=400R\text{ ln }2. $



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