Thermodynamics Question 237

Question: An insulated container of gas has two chambers separated by an insulating partition. One of the chambers has volume V1 and contains ideal gas at pressure P1 , and temperature T1 The other chamber has volume V2 and contains ideal gas at pressure P2 and temperature T2 If the partition is removed without doing any work on the gas, the final equilibrium temperature of the gas in the container will be

Options:

A) T1T2(P1V1+P2V2)P1V1+P2V2

B) P1V1T1+P2V2T2P1V1+P2V2

C) P1V1T2+P2V2T1P1V1+P2V2

D) T1T2(P1V1+P2V2)P1V1T1+P2V2T2

Show Answer

Answer:

Correct Answer: A

Solution:

[a] Here Q=0 and W=0.

Therefore from first law of thermodynamics ΔU=Q+W=0

Internal energy of the system with partition = Internal energy of the system without partition. n1CvT1+n2CvT2=(n1+n2)CvT

T=n1T1+n2T2n1+n2

But n1=P1V1RT1 and n2=P2V2RT2

T=P1V1RT1×T1+P2V2RT2×T2P1V1RT1+P2V2RT2=T1T2(P1V1+P2V2)P1V1T2+P2V2T1



NCERT Chapter Video Solution

Dual Pane