Thermodynamics Question 128

Question: The specific heat of hydrogen gas at constant pressure is $ C _{P}=3.4\times 10^{3}cal/kg{{}^{o}}C $ and at constant volume is $ C _{V}=2.4\times 10^{3}cal/kg{{}^{o}}C. $ If one kilogram hydrogen gas is heated from $ 10^{o}C $ to $ 20^{o}C $ at constant pressure, the external work done on the gas to maintain it at constant pressure is

[MP PMT 1995; DPMT 2001]

Options:

A) $ 10^{5} $ cal

B) $ 10^{4} $ cal

C) $ 10^{3} $ cal

D) $ 5\times 10^{3} $ cal

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Answer:

Correct Answer: B

Solution:

From FLOT DQ = DU + DW Work done at constant pressure $ {{(\Delta W)} _{P}}={{(\Delta Q)} _{P}}-\Delta U $

$ {{(\Delta Q)} _{P}}-{{(\Delta Q)} _{V}} $

(As we know $ {{(\Delta Q)} _{V}}=\Delta U $ )

Also $ {{(\Delta Q)} _{P}}=mc _{P}\Delta T $

and $ {{(\Delta Q)} _{V}}=mc _{V}\Delta T $

Therefore $ {{(\Delta W)} _{P}}=m(c _{P}-c _{V})\Delta T $

Therefore $ {{(\Delta W)} _{P}}=1\times (3.4\times 10^{3}-2.4\times 10^{3})\times 10=10^{4}cal $



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