Some Basic Principles Of Organic Chemistry Question 69

Question: An organic compound gave C = 92.31% and $ H=7.69% $ . If molecular weight of the compound is 78, its molecular formula is

Options:

A) $ C_6H_6 $

B) $ C_7H_7 $

C) $ C_6H_{18} $

D) $ C_8H_{20} $

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Answer:

Correct Answer: A

Solution:

Element No.of Moles Simple Ratio
C = 92.31 92.31/12 = 7.69 1
H = 7.69 7.69/1 = 7.69 1

Hence, CH Empirical formula mass of CH = 13 $ n=\frac{Mol\text{.mass}}{Emp\text{.},mass}=\frac{78}{13}=6 $

Molecular formula = $ {{(CH)}_6}=C_6H_6 $ .



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